The Tm and both Cu atoms lie on mirror planes. The Tm atom is seven-coordinate with a capped distorted trigonal–prismatic coordination geometry, while the Cu atoms adopt trigonal CuBrN2 and tetrahedral CuBr3N coordination modes, respectively. The Cu atom in the trigonal coordination environment is disordered over two sites of equal occupancy. The crystal structure is constructed from two distinct units of dimeric [Tm2(μ2-OH(IN)6(H2O)4] cores (IN = isonicotinate) and one-dimensional inorganic [Cu4Br3]n chains, which are linked together, forming heterometallic Cu–halide–lanthanide–organic layers.A new thulium(III)–copper(I) heterometallic coordination polymer, [Cu DOI: 10.1107/S1600536808028675/sj2536Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808010763/cv2399Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809034916/pv2195Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The zinc(II) metal centre displays a distorted octahedral coordination environment provided by N atoms of two bidentate chelating and two monodentate 5-(2-aminophenyl)tetrazolate ligands. These ligands act as bridges, linking adjacent Zn atoms into polymeric criss-crossed chains parallel to the [110] and [The polymeric title compound, [Zn(C DOI: 10.1107/S1600536808021946/rz2234Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ribbons are connected by C—H⋯O hydrogen bonds and van der Waals interactions.In the title structure, [Pb(C DOI: 10.1107/S1600536810002199/kp2247Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809032413/hb5048Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The four O atoms belonging to two 2,4-pentanedionate anions lie in the equatorial plane and the two N atoms occupy the axial coordination sites.In the title compound, [Mn(C DOI: 10.1107/S1600536808038440/hb2842Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809042160/pv2218Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The 1,1′-diimidazole ligand and the cyclohexane-1,4-dicarboxylate dianion bridge metal centres, forming a two-dimensional  network. The network is consolidated by O—H⋯O hydrogen bonds between the statistically occupied water molecules and O atoms of the two carboxylate groups.In the title coordination polymer, {[Ni(C DOI: 10.1107/S1600536809004024/bt2863Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


One C atom of one ethyl group is disordered with site occupancies of 0.61 (3):0.39 (3).The Sn atom of the title compound, [Sn(C DOI: 10.1107/S1600536808032388/tk2313Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The cations lie in sheets parallel to (The asymmetric unit of the title compound, (C DOI: 10.1107/S1600536808043523/bt2834Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809034795/hb5080Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The coordination bonds give rise to a layer structure parallel to (010).In the title coordination polymer, [CuI(C DOI: 10.1107/S1600536808031188/ng2496Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808007472/cs2070Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The zigzag chains, extending parallel to [011], are further packed into a three-dimensional network by hydrogen bonds.The title compound, {[Zn(C DOI: 10.1107/S1600536808035514/bq2094Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Zh. Str DOI: 10.1107/S1600536808009719/fi2061Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Individual [Zn(N3)2(dpa)]n chains are connected into supramolecular layers via N—H⋯N hydrogen bonding between the central amine groups of the dpa ligands and terminal unligated azide N atoms. The azide ligands in one supramolecular layer penetrate through the neighboring layers above and below, allowing stacking into a three-dimensional structure.In the title compound, [Zn(N DOI: 10.1107/S1600536809051599/zl2257Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal packing, the arrays are linked by adjacent ring motifs, together with additional intermolecular O—H⋯O interactions, into a three-dimensional network.A monoclinic polymorph of the title compound, [Na(Chino 1993. Bull. C DOI: 10.1107/S1600536810000681/tk2611Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The two Cu atoms, one with an N2P2 ligand set and the other with an NP2 ligand set, are bridged by two bis(diphenylphosphino)methane ligands, forming an eight-membered ring.The title dinuclear copper(I) complex, {[Cu DOI: 10.1107/S1600536809040896/jh2105Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809032048/hb5044Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Two cations are linked into a centrosymmetric dimer via three bridging carboxylate groups of 2,4-difluorobenzoate ligands. Each Gd3+ ion is nine-coordinated by seven O atoms and two N atoms.In the title compound, [Gd DOI: 10.1107/S1600536808004431/cf2184Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Each cation links two [PMo12O40]3− anions, which link three cations through N—H⋯O hydrogen bonds, generating an infinite supramolecular chain-like structure.In the title compound, (C DOI: 10.1107/S1600536808014463/cs2077Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536810003727/sj2718Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Mn atom lies on an inversion centre. The distorted octahedral Mn environment contains two planar trans-related N,N′-chelating 5-(2-pyridyl)tetrazolate ligands in the equatorial plane and two axial water molecules. O—H⋯N hydrogen bonds generate an infinite three-dimensional network.The title compound, [Mn(C DOI: 10.1107/S1600536808010106/dn2338Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The CuII ion is in a slightly distorted square-pyramidal coordination environment. In the crystal structure, intermolecular O—H⋯O hydrogen bonds connect complex molecules into chains along [001].The title complex, [Cu(C DOI: 10.1107/S1600536808029449/lh2688Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The two 4,4′-ethylenedibenzoate dianions are located on inversion centres bridging two neighboring CdII centres. O—H⋯O hydrogen-bonding interactions further stabilize the crystal structure.  The DMF molecule is equally disordered about a center of inversion.In the title compound, [Cd(C DOI: 10.1107/S1600536809024714/bt2984Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The new β-polymorph is 1.05 times denser than the previously known polymorph [Rae et al.  was obtained for an active pharmaceutical ingredient, bismuth tribenzoate, [Bi(C al. 1998. Acta Cr DOI: 10.1107/S1600536810035543/rk2224Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal, O—H⋯O hydrogen bonds help to establish the packing.In the title compound, [Zn(C DOI: 10.1107/S1600536809034473/hb5073Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The coordination around mercury is completed by two bromido ligands resulting in a distorted tetrahedral arrangement.In the title polymeric complex, [HgBr DOI: 10.1107/S1600536808030055/si2110Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Each NiII atom is chelated by two oxalate ligands and one 2,2′-bipyridine, forming a slightly distorted octahedral geometry. Oxlate acts as a bridge to link neighbouring pairs of NiII cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning.The title compound, [Ni(C DOI: 10.1107/S1600536808028389/cf2213Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal, associations of two cations and one anion linked by N—H⋯Br hydrogen bonds occur.In the title compound, (C DOI: 10.1107/S160053680901705X/hb2965Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The dihedral angle between rings of anion is 86.1 (1)°.In the crystal of the title hydrated salt, C DOI: 10.1107/S1600536809033856/ng2622Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809020340/tk2467Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809041919/fi2085Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809030943/bh2240Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Nb atom is situated on a site of symmetry 6               − anion has crystallographic fourfold symmetry.The title complex, [Nb(C DOI: 10.1107/S1600536808026627/lx2067Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, O—H⋯O hydrogen bonds lead to associations of one metal complex and two diglyme molecules.In the title 1:2 adduct, [SnCl DOI: 10.1107/S1600536808029917/bt2792Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In addition, the dinuclear species is stabilized by two hydrogen-bonded perchlorate anions.Each Cu atom in the dinuclear centrosymmetric title complex, [Cu DOI: 10.1107/S1600536807068663/tk2238Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Intermolecular N—H⋯N hydrogen bonds link neighboring molecules into extended chains parallel to [100].In the title complex, [Ni(C DOI: 10.1107/S1600536808028171/bv2105Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The axial thiocyanate ligands act in a μ1,3-bridging mode to connect symmetry-related CdII ions into one-dimensional chains along [010]. In addition, there are intermolecular C—H⋯O contacts between chains.In the title crystal structure, [Cd(NCS)(NO DOI: 10.1107/S1600536808032297/lh2703Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octahedral geometry. The title complex, [Ni DOI: 10.1107/S1600536810003697/rz2413Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The NiII atoms are linked to each other, forming an infinite chain parallel to (In the title complex, [Ni(C DOI: 10.1107/S1600536808030377/dn2372Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


This results in alternating corrugated inorganic and organic layers in the crystal.In the title molecular salt, (C DOI: 10.1107/S160053681001812X/hb5451Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ZnII ion is coordinated by two bpp and two ip ligands in a distorted tetrahedral environment. Each ligand coordinates in a bridging mode to connect ZnII ions into a three-dimensional diamondoid-type structure.The title compound, [Zn(C DOI: 10.1107/S1600536808001621/lh2583Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Cu atom is 0.1801 (11) Å above the N3O mean basal plane.The Cu atom of the title complex, [Cu(C DOI: 10.1107/S1600536809014573/rk2135Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


One of the sulfonate O atoms is disordered over two positions [ratio 0.70 (5):0.30 (5)].In the title compound, [Pd(C DOI: 10.1107/S1600536809032760/bx2229Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S160053680902234X/bh2230Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ReI atoms are in a slightly distorted octahedral environment, whereas the ReVII atoms show the typical tetrahedral coordination mode. The dihedral angle between the two bipyridine groups is 34.3 (7)°.The title compound, [Re DOI: 10.1107/S160053680800490X/at2546Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ZnII atoms show distorted tetrahedral coordination environments. Adjacent molecules are linked by N—H⋯Cl hydrogen bonds, forming a three-dimensional network.The title compound, [ZnCl DOI: 10.1107/S1600536809052738/bt5133Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The P and one S atom of each trimethyl trithiophosphite ligand are employed for coordination. The molecular structure exhibits the rare motif of copper(I) bridged by two trifluoromethanesulfonate anions generating eight-membered rings.The title compound, [Cu DOI: 10.1107/S1600536808041809/lh2742Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The tethering 3-bpmp ligands promote the formation of [ZnCl2(3-bpmp)]n chains situated parallel to (via C—H⋯Cl interactions to form supramolecular layers, which in turn stack to construct the three-dimensional crystal structure.In the title compound, [ZnCl DOI: 10.1107/S1600536809013877/ng2573Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The coordinated water molecule plays an important role in crystal packing consolidation via O—H⋯O hydrogen bonding.In the title compound, [Sn DOI: 10.1107/S1600536808043614/cv2496Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Each metal atom is chelated by two Schiff base anions in a distorted square-planar coordination environment.The asymmetric unit of the crystal structure of the title compound, [Ni(C DOI: 10.1107/S1600536809020790/xu2537Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The N-heterocyclic carbene (NHC) metallacrown ether ligand binds to the Pd atom in a trans orientation through the carbene C atoms of the two imidazole rings and generates a 25-membered chelate ring. Two mutually trans S-bound thiocyanate ligands complete the coordination.The coordination geometry of the Pd atom in the title compound, [Pd(SCN) N-heterocyclic carbene ligands and their complexes, see: Herrmann ] = 0.066                           wR(F                           2) = 0.218                           S = 1.05                           8672 reflections566 parameters61 restraintsH-atom parameters constrainedmax = 0.78 e Å−3                        Δρmin = −1.31 e Å−3                        Δρ                                 DIFRAC  used to solve structure: SHELXS97 (Sheldrick, 2008SHELXL97 (Sheldrick, 2008ORTEP-3 for Windows (Farrugia, 1997SHELXL97.Data collection: 10.1107/S1600536809014615/sj2617sup1.cif            Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809014615/sj2617Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Three of the C atoms of the n-butyl group are disordered over two sites with equal occupancies.The Sn atom in the title compound, [Sn(C DOI: 10.1107/S1600536810005830/lh2995Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The oxalate and pyrazine-2-carboxylate ligands bridge the CeIII ions, forming a two-dimensional structure. In addition, intermolecular O—H⋯O and O—H⋯N hydrogen bonds connect the two-dimensional structure into a three-dimensional network.In the hydrothermally synthesized title compound, [Ce(C DOI: 10.1107/S1600536808029164/lh2687Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Mn2+ cation is surrounded by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands in a distorted octahedral coordination. In the heteropolyanion, two O atoms of the central PO4 group (The asymmetric unit of the title compound, [Mn(C DOI: 10.1107/S160053681000320X/wm2301Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The structural parameters compared with those in [(η5-Me5Cp)2Zr(TePh)2] [Howard, Trnka & Parkin  and by more acute Zr—Te—C (∼5°) angles, although the Zr—Te distances are essentially the same. The crystal studied exhibited some inversion twinning.The structure of the title compound, [Zr(Crkin 1995. Inorg.  DOI: 10.1107/S1600536808009574/sj2480Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The imino NH groups participate in intermolecular N—H⋯O hydrogen bonds.The title complex, [Zn(NO DOI: 10.1107/S1600536809037672/fj2244Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The eight-coordinate geometry approximates a square antiprism. Hydrogen bonds of the O—H⋯O type connect the uncoordinated water molecules to the dinuclear species, forming a three-dimensional network.The title dinuclear compound, [Tb DOI: 10.1107/S1600536809052489/xu2706Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808013792/im2062Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Two of the water molecules are disordered over three sites in a 0.68:0.55:0.77 ratio.The crystal structure of the title compound, (C DOI: 10.1107/S1600536810018325/bt5270Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


A slightly distorted trigonal-bipyramidal SnC3O2 coordination geometry arises for the metal, with the O atoms in the axial sites. Weak C—H⋯O hydrogen bonds help to stabilize the packing.The polymeric structure of the title compound, [Sn(CH DOI: 10.1107/S1600536809051587/hb5258Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808002341/dn2314Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Sn atom is six-coordinate with a distorted octahedral geometry. Additional O—H⋯O hydrogen bonding leads to stabilization of the crystal structure.The title compound, [Sn DOI: 10.1107/S1600536808032832/sg2266Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Each Sb atom exhibits a slightly distorted trigonal-bipyramidal geometry, with the O atom in the apical site. The crystal structure is stabilized by intermolecular C—H⋯O hydrogen bonds, forming a three-dimensional network.The asymmetric unit of the title compound, [Sb(C DOI: 10.1107/S1600536808040816/rz2272Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The complex features a Pt(II) atom coordinated by two Cl and two P atoms, yielding a slightly distorted cis square-planar geometry.The title compound, [PtCl DOI: 10.1107/S1600536809042226/fi2086Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809000270/at2697Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The five-membered chelating glycinate ring assumes an envelope conformation. The complex molecules are assembled by intermolecular N—H⋯O hydrogen bonding.In the crystal structure of the title compound, [Co(C DOI: 10.1107/S1600536808013135/xu2418Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials: interactive version of Fig. 3            Enhanced figure:


The Zn atom lies on a special position of site symmetry 2.The Zn atom in the title compound, [Zn(C DOI: 10.1107/S1600536808002213/hg2370Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The crystal packing is consolidated by additional O—H⋯O and N—H⋯O hydrogen bonds.The novel pentaborate with a transition-metal complex as counter-cation and with water of crystallization, tris(ethylenediamine)cobalt(II) bis dihydrate, [Co(C DOI: 10.1107/S1600536809007296/pv2140Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


All interatomic distances, angles and the hydrogen bond geometry are very similar for the three structures.The title compound, [Tb(C DOI: 10.1107/S1600536809001494/at2682Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The dihedral angle between the planes of the two NiNC3O chelate rings is 14.37 (12)°.In the title complex, [Ni(C DOI: 10.1107/S1600536809019965/bt2968Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The hydrocarbon chains are in the fully extended all-trans conformation and are arranged in a tail-to-tail double bilayer.The structure of the title compound, poly[di-μ-pentanoato-zinc(II)], [Zn{CH DOI: 10.1107/S1600536808008283/cf2188Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536810010895/bt5207Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal, molecules are linked by N—H⋯Cl hydrogen bonds, generating (100) sheets containing R               2               2(8) loops.In the title compound, [ZnCl DOI: 10.1107/S1600536810012274/hb5384Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In common with the monoclinic polymorph [Howie et al.  hydrogen-bonding interactions generate a three-dimensional network.The asymmetric unit of the title hydrate, 2[Sn(H al. 2005. Inorg.  DOI: 10.1107/S1600536810006021/hb5334Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S160053680900988X/bx2197Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials: interactive version of Fig. 1            Enhanced figure:


The acetate bridges link adjacent CuII cations, forming a chain. The crystal structure involves O—H⋯O hydrogen bonds.In the title compound, [Cu(CH DOI: 10.1107/S1600536808016073/cf2197Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Cd atoms are connected by two dicyanamide ligands, resulting in a neutral chain propagating parallel to [010].In the title compound, [Cd(C DOI: 10.1107/S1600536809046364/pv2226Isup2.hklStructure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF reportAdditional supplementary materials:


The molecules are assembled via intermolecular N—H⋯O hydrogen-bonding interactions into a three-dimensional network.In the title mononuclear complex, [Co(C DOI: 10.1107/S1600536808005722/ng2407Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Weak C—H⋯O contacts generate dimeric units via crystallographic inversion centres.In the title complex, [Sb(C DOI: 10.1107/S1600536808029632/si2109Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Mn^II^ cation has a distorted octahedral coordination geometry. The 1,3-di(tetrazol-5-yl)benzene ligand is planar. All H atoms bonded to O atoms participate in hydrogen bonds, which link the molecules into a framework structure.The title compound, [Mn(C Data collection: 10.1107/S1600536808028316/ez2139sup1.cif            Crystal structure: contains datablocks global. DOI: 10.1107/S1600536808028316/ez2139Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The trans-N2S4 donor set defines a distorted octahedral geometry.In the title complex, [Ni(C DOI: 10.1107/S1600536809050223/tk2572Isup2.hklStructure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF reportAdditional supplementary materials:


The word "Mediates" was misspelled in the article title. The correct title is: CX₃CR1 Is Expressed by Human B Lymphocytes and Mediates CX₃CL1 Driven Chemotaxis of Tonsil Centrocytes. The correct citation is: Corcione A, Ferretti E, Bertolotto M, Fais F, Raffaghello L, et al. (2009) CX₃CR1 Is Expressed by Human B Lymphocytes and Mediates CX₃CL1 Driven Chemotaxis of Tonsil Centrocytes. PLoS ONE 4(12): e8485. doi:10.1371/journal.pone.0008485


The coordination of Cu(I) is slightly distorted tetrahedral.The title compound, [CuBr(C DOI: 10.1107/S1600536808012439/dn2345Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The isophthalate ligands bridge the metal ions to form polymeric zigzag chains extending along the b axis. Weak C—H⋯O interactions contribute to the crystal packing stability.In the title compound, [Co(C DOI: 10.1107/S1600536808030778/rz2249Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Both Sn centres exhibit similar distorted trigonal–bipyramidal [C3SnO2] coordination, with the O atoms of the carboyxlate ligands in trans positions.The title compound, [Sn(C DOI: 10.1107/S160053680802028X/wm2181Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The coordination geometry of the ZnII ion is slightly distorted square-planar, formed by two N atoms and two O atoms from the L ligand.The title compound, [Zn(C DOI: 10.1107/S1600536809038616/hg2565Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, weak bifurcated C—H⋯O hydrogen bonds involving the carbonyl O atoms as acceptors result in R               2               2(7) ring motifs.In the title compound, C DOI: 10.1107/S1600536810005404/lh2990Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The molecules are linked together via hydrogen bonds involving the solvent water and methanol molecules.In the title complex, [Gd(C DOI: 10.1107/S1600536808001931/om2208Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The SnO4NC2 centre has a distorted pentagonal–bipyramidal geometry with the C atoms in the axial positions.The title compound, [Sn(CH DOI: 10.1107/S1600536807067165/hb2677Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The fully deprotonated PDC anion acts a μ3-bridging ligand, establishing a chain structure along the a axis. These polymeric chains are connected into a three-dimensional framework via several intermolecular O—H⋯O hydrogen bonds.In the title coordination polymer, {[Mn(C DOI: 10.1107/S1600536808029413/sg2261Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Acta Cr DOI: 10.1107/S1600536810006306/hy2284Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The dihedral angle between the pyridine and benzene rings is 15.15 (13)°.In the title compound, [ZnI DOI: 10.1107/S1600536808020680/rz2225Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The compound crystallizes with one CH2Cl2 molecule per asymmetric unit. The benzylamine ligand and the ReI centre form a non-planar six-membered chelate ring.In the crystal structure of the title compound, [ReCl(C DOI: 10.1107/S160053680706802X/zl2094Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.In the title compound, (C DOI: 10.1107/S1600536808037616/pk2131Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the title compound, C DOI: 10.1107/S1600536808025300/fj2138Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


C—H⋯O hydrogen bonds connect the complex molecules into a three-dimensional supramolecular structure.In the title compound, [Zn(C DOI: 10.1107/S1600536808009483/hy2125Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Concomitant treatment in addition to intervention may influence the primary outcome, especially in complex interventions such as surgical trials. Evidence-based standards for perioperative care after distal pancreatectomy, however, have been rarely defined. This study's objective was therefore to identify and analyse the current basis of evidence for perioperative management in distal pancreatectomy.A standardised questionnaire was sent to 23 European centres recruiting patients for a randomized controlled trial (RCT) on open distal pancreatectomy that would compare suture versus stapler closure of the pancreatic remnant . Perioperative strategies  were assessed. Moreover, a systematic literature search in the Medline database was performed and retrieved meta-analyses and RCTs were reviewed.All 23 centres returned the questionnaire. Consensus for thoracic epidural catheters (TECs), pain treatment and transverse incisions was found, as well as strong consensus for the placement of intra-abdominal drainages and perioperative single-shot antibiotics. Also, there was consensus that bowel preparation, somatostatin application, postoperative nasogastric tubes and intravenous feeding might not be beneficial. The literature search identified 16 meta-analyses and 19 RCTs demonstrating that bowel preparation, somatostatin therapy and nasogastric tubes can be omitted. Early mobilisation, feeding and TECs seem to be beneficial for patients. The value of drainages remains unclear.Most perioperative standards within the centres participating in the DISPACT trial are in accordance with current available evidence. The need for drainages requires further investigation.Clinical trial registration: ISRCTN 18452029 Short-term outcomes after major abdominal surgery are influenced by indication, surgical intervention, the surgeons' expertise, hospital volume and perioperative management -5. In orA recent study of 617 consecutive pancreatic resections demonstrated local complications to be more frequent than systemic complications . Thus, tTwenty-three European centres participating in the DISPACT trial were evaluated using a standardized questionnaire to evaluate perioperative management  OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH] NOT child [MESH] NOT infant [MESH]) AND  AND  OR ((singl* [tw] OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH]) AND (somatostatin [tw] OR octreotide [tw] OR vapreotide [tw] OR lanreotide [tw]) AND  OR ((singl* [tw] OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH])(Surgery [MESH]) AND  AND  OR ((singl* [tw] OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH]) AND  AND  OR ((singl* [tw] OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH] NOT child [MESH] NOT infant [MESH]) AND (Nasogastric decompression [tw] OR nasogastric tube [tw]) AND  OR ((singl* [tw] OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH] NOT child [MESH] NOT infant [MESH])(Surgery [MESH]) AND  AND  OR ((singl* [tw] OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH] NOT child [MESH] NOT infant [MESH]) AND  AND  OR ((singl* [tw] OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH] NOT child [MESH] NOT infant [MESH]) AND (mobilisation [tw] OR mobilization [tw] OR postoperative mobilisation [tw] OR patient mobilisation [tw] OR postoperative mobilization [tw] OR patient mobilization [tw]) AND  OR ((singl* [tw] OR doubl* [tw] OR tripl* [tw]) AND (mask* [tw] OR blind* [tw])) OR placebos [MESH] OR placebo* [tw] OR random* [tw] OR research design [mh:noexp] OR Meta-Analysis [ptyp] OR systematic review [tw] NOT  NOT case reports [pt] NOT Comment [PT] NOT letter [PT] NOT child [MESH] NOT infant [MESH] NOT child [MESH] NOT infant [MESH])Survey on peri-operative standards in distal pancreatectomy. A copy of the research instrument used for the survey.Click here for fileMeta-analyses and randomized controlled trials on perioperative management. Appendix 1 summarizes relevant data from the meta-analyses and randomized controlled trials found by the literature search of best practice.Click here for file


The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.The title compound, [Sr(C DOI: 10.1107/S1600536808012373/nc2102Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536810015758/hy2302Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Three dinucleating O,N:N′,O′-donor ligands provide three diazine (=N—N=) bridges between the metal ions, yielding a binuclear triple helicate structure with crystallographic C               2 symmetry, the rotation axis bisecting one N—N bond.In the title binuclear iron(III) complex, [Fe DOI: 10.1107/S1600536808027438/cf2210Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In addition, each AgI atom is coordinated by one chelating 2,2′-bipyridine ligand, giving a distorted trigonal coordination environment.The title complex, [Ag DOI: 10.1107/S1600536809014871/at2766Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ligand bridges two AgI atoms, forming a polymeric zigzag chain propagating parallel to [001]. The uncoordinated water molecule is involved in hydrogen bonds with sulfonate O atoms.In the title compound, {[Ag(C DOI: 10.1107/S1600536810012596/hy2295Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The SnIV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding interactions involving the hydroxyl substituents.The title compound, [Sn(C DOI: 10.1107/S1600536809023150/tk2461Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809027044/ng2598Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Tetrachloridoferrate(III) anions lie between these chains, accepting N—H⋯Cl hydrogen bonds from both H atoms of the picolinamidium –NH2 group.The title compound, (C DOI: 10.1107/S1600536809040148/zq2012Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The polymeric three-dimensional structure is stabilized by intermolecular O—H⋯O hydrogen bonds.In the title coordination polymer, [La(C DOI: 10.1107/S1600536809020479/rz2328Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


These aggregate into the three-dimensional structure via N—H⋯O hydrogen-bonding mechanisms imparted by 4,4′-iminodipyridinium dications situated between the layers.In the title salt, {(C DOI: 10.1107/S1600536808038348/tk2326Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536810005829/ci5035Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The crystal packing exhibits weak intermolecular C—H⋯Br interactions.In the title compound, [PdBr DOI: 10.1107/S1600536809001986/cv2489Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ZnII atom is coordinated in a distorted tetrahedral environment by four O atoms from four 2,4-dichlorophenoxyacetate ligands. Each ligand bridges two ZnII atoms, forming a polymeric chain along the a axis. Adjacent chains are connected via C—H⋯Cl hydrogen bonds.The title polymeric compound, [Zn(C DOI: 10.1107/S1600536810015977/ci5084Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The twisted molecules pack in parallel regions (ab plane) which then form a herringbone pattern along c.The racemic title compound, C DOI: 10.1107/S1600536808014803/bq2079Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The methyl group of the benzoic acid molecule is disordered over two sites in a 0.563 (17):0.437 (17) ratio. In the title compound, [Ni(C DOI: 10.1107/S1600536809044705/hb5141Isup2.hklStructure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF reportAdditional supplementary materials:


In the unique cation, the dihedral angle between the benzene and pyridine rings is 7.1 (2) Å.In the title complex, (C DOI: 10.1107/S1600536809015360/lh2806Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, intermolecular N—H⋯I hydrogen bonds link cations and anions into a three-dimensional network.In the title compound, [Cd(dien) DOI: 10.1107/S1600536808008040/lh2585Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809031389/hb5029Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The 4,4′-bipyridine ligands bridge CoII ions into a one-dimensional chain structure. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dianions are completely disordered about an inversion center.In the title complex, {[Co(C DOI: 10.1107/S1600536809021552/lh2836Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The amino group forms a hydrogen bond to the pyrazine N-4 atom of an adjacent molecule, forming a chain motif.The two aromatic systems in the title compound, C DOI: 10.1107/S160053680803729X/sg2277Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ligands bridge CdII ions, forming one-dimensional chains along [001], which are connected by N—H⋯N and N—H⋯S hydrogen bonds into a three-dimensional network.In the title compound,  DOI: 10.1107/S160053680902371X/pk2170Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808004248/su2044Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The metal atoms are bridged by the pySO3 ligands to form a one-dimensional chain. The chains are further connected into a three-dimensional architecture via hydrogen bonds.In the title polymeric complex, [Mn(C DOI: 10.1107/S1600536808012282/gk2137Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The crystal structure displays the classical O—H⋯O intermolecular hydrogen bonding typical for carboxylic acids forming dimers. Symmetry-related dimers are, in turn, linked through head-to-tail pairs of intermolecular N—H⋯O interactions, giving rise to a zigzag chain along the c axis.The title compound, C DOI: 10.1107/S1600536808035721/lh2721Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Co centre is in a distorted tetrahedral coordination by three N atoms of three different triazole ligands and one O atom of the 3,5-dinitrobenzoate anion.The title compound, [Co(C DOI: 10.1107/S160053680804155X/bt2826Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536810013759/zs2034Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The NaI cation is located on a threefold rotation axis and is surrounded by six O atoms from three opc anions. The opc anions link the Mn and Na cations, forming a three-dimensional polymeric structure. The uncoordinated water molecule, located on a threefold rotation axis, is equally disordered over two sites. The three-dimensional network is consolidated by N—H⋯O hydrogen bonds.In the crystal structure of the title compound, {[MnNa(C II and CoII complexes, see: Zhang et al. 3]·H2O = 0.033                           wR(F                           2) = 0.099                           S = 1.16                           1315 reflections103 parameters1 restraintH-atom parameters constrainedmax = 0.35 e Å−3                        Δρmin = −0.49 e Å−3                        ΔρAbsolute structure: Flack 1983, 649 FriFlack parameter: −0.01 (3)                                 PROCESS-AUTO (Rigaku, 1998PROCESS-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002SIR92 (Altomare et al., 1993SHELXL97 (Sheldrick, 2008ORTEP-3 (Farrugia, 1997WinGX (Farrugia, 1999Data collection: 10.1107/S1600536810002953/ng2724sup1.cif            Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810002953/ng2724Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809027196/dn2466Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The crystal packing is stabilized by O—H⋯O hydrogen bonds.In the title compound, [Cu(C DOI: 10.1107/S1600536808009495/bt2691Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808041408/hg2447Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The bridging function of the iodide ions leads to a chain structure propagating in [001].In the title coordination polymer, [CdI DOI: 10.1107/S1600536810014091/hb5403Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The thiocyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.In the cyrstal structure of the title compound, [Cu(NCS)(C DOI: 10.1107/S1600536808041925/lh2744Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The edta ligands link the neodymium metal centres, forming polymeric chains running along the a axis of the unit cell. These chains are further assembled via intermolecular O—H⋯O hydrogen-bonding interactions into a three-dimensional supramolecular network.In the title complex, [Nd(C DOI: 10.1107/S1600536808026445/bg2202Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809035041/jh2099Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal packing, a three-dimensional network is constructed via hydrogen-bonding involving the water molecules, uncoordinated imidazole N atom, protonated pyridine N and carboxylate O atoms.In the title complex, [Fe(C DOI: 10.1107/S160053680902337X/kp2221Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808015390/sj2506Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808012828/dn2343Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials: interactive version of Fig. 1            Enhanced figure:


The crystal structure is stabilized by a network of O—H⋯O hydrogen bonds, resulting in a two-dimensional supramolecular structure.In the neutral title complex, [Fe(C DOI: 10.1107/S1600536808042529/ng2527Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar.The title complex, [Ir DOI: 10.1107/S1600536808007216/cf2181Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808035460/tk2320Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The non-H atoms of the equatorial plane are coplanar, with a mean deviation of 0.0355 (2) Å. The FeII cation lies on an inversion centre. Thus, the asymmetric unit comprises one half-molecule.In the title compound, [Fe(N DOI: 10.1107/S1600536808018539/kp2177Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Ni2+ cation is surrounded in a slightly distorted octahedral coordination by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands. In the heteropolyanion, two O atoms of the central SiO4 group (The asymmetric unit of the title compound, [Ni(C DOI: 10.1107/S1600536810000978/wm2297Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808020850/ng2470Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal, the molecules form hydrogen bonded chains propagating in [100] linked by O—H⋯O interactions.  Further O—H⋯O bonds cross-link the chains.The title compound, C DOI: 10.1107/S1600536809017656/fl2248Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808002201/lh2588Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The LaIII atom is coordinated by nine O atoms from three carboxylate, three sulfonate and two hydroxyl groups, and one water molecule, forming a distorted trigonal-prismatic square-face tricapped geometry.The title compound, [La(C DOI: 10.1107/S1600536809007879/is2373Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The carboxylate ligands bridge pairs of gadolinium(III) ions, forming a zigzag chain along [100]. Hydrogen bonds link the chains into sheets parallel to (001).In the title compound, [Gd(C DOI: 10.1107/S1600536808012981/om2225Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, N—H⋯N hydrogen bonds help to consolidate the packing.In the title compound, [Mn(N DOI: 10.1107/S1600536808017984/hb2744Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809018364/fi2078Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The four-coordinate AgI ion adopts a tetrahedral geometry, being bonded to two N atoms from two bridging isonicotinate ligands and two O atoms from two acetate ligands. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network.In the title homochiral three-dimensional heterometallic complex, [AgSm(C DOI: 10.1107/S1600536809048430/pv2235Isup2.hklStructure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF reportAdditional supplementary materials:


In the crystal structure, cations and anions are linked by intermolecular N—H⋯Cl hydrogen bonds, forming a three-dimensional network.In the title compound, (C DOI: 10.1107/S1600536810007877/rz2412Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809022417/hb2992Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials: interactive version of Fig. 1            Enhanced figure:


The three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the CuII atom is 31% distorted from trigonal-bipyramidal .The title compound, [CuCl DOI: 10.1107/S1600536810037025/xu5030Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The metallabicyclic ring system is essentially planar (maximum deviation 0.059 Å).The crystal structure of the title compound, [Ru(C DOI: 10.1107/S1600536808040944/lh2738Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The two N-heterocycles both chelate the metal atom.The chloride and chlorodifluoroacetate anions occupy  DOI: 10.1107/S1600536808010829/sg2236Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Ni2+ cation is in a distorted octahedral environment, coordinated by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands. In the one-electron reduced heteropolyanion, two O atoms of the central PO4 group (M—N bond lengths, whereas all other bond lengths, angles and the hydrogen-bonding motifs are very similar.The hydrothermally prepared title compound, [Ni(C DOI: 10.1107/S1600536810005945/wm2306Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The carboxylate groups of pyrazine-2-carboxylate and oxalate ligands link the lanthanum metal centres, forming layers parallel to (10In the title complex, [La(C DOI: 10.1107/S1600536808041664/dn2413Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808025452/hy2145Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chlorodifluoromethyl groups are also disordered over two sites for their halogen atoms (occupancy ratios 0.72:0.28 and 0.70:0.30).In the title salt, [Ag(C DOI: 10.1107/S1600536808014128/bq2076Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The three O atoms are arranged fac, as are the three S atoms.In the title compound, [Co(C DOI: 10.1107/S1600536808011598/hy2130Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Corner-sharing PbCl6 octahedra extend parallel to the ac plane. Adjacent layers are staggered relative to one another, with diammonium cations separating these layers. The cations exhibit via N—H⋯Cl hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.The title compound, {(C DOI: 10.1107/S1600536810016818/wm2339Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The dihedral angle between the two essentially planar quinoline ring systems is 45.02 (9)°. In the crystal structure, an extensive O—H⋯O hydrogen-bonding network forms layers parallel to the ab plane.In the title compound, [Cu(SO DOI: 10.1107/S1600536808001980/lh2587Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The resulting geometry is distorted octahedral within a ClN2O3 donor set.In the title complex, [Fe(C DOI: 10.1107/S1600536809031432/tk2520Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the chain, the ZnII atom adopts a slightly distorted octahedral coordination geometry involving four water molecules at the equatorial positions. The noncoordinated benzene-1,4-dicarboxylate anion, which is also located on a twofold rotation axis, bridges adjacent chains through O—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network.In the title compound, {[Zn(C DOI: 10.1107/S1600536809019412/is2415Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The hydroxyl group acts as a donor, forming an intramolecular O—H⋯N hydrogen bond.In the title compound, [Zn(C DOI: 10.1107/S1600536809001949/hy2173Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Both PbBr6 octahedra and the organic cation exhibit via N—H⋯Br hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.The title compound, {(C DOI: 10.1107/S1600536810016806/wm2338Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S160053680904495X/hb5192Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, molecules are linked by bifurcated N—H⋯ hydrogen bonds, generating [001] chains.In the title compound, C DOI: 10.1107/S1600536810010810/hb5367Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809024015/tk2481Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The piperidine ring adopts a distorted boat conformation in both molecules, in which the N atom assumes an almost planar configuration.The asymmetric unit of the title compound, C DOI: 10.1107/S1600536809045358/ci2956Isup2.hklStructure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF reportAdditional supplementary materials:


The Na atoms are disordered over three sites .The crystal structure of the title compound, 2Na DOI: 10.1107/S1600536808024331/bt2752Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The bridging dca anions lead to a polymeric chain propagating in [100].In the title compound, [Cd(C DOI: 10.1107/S1600536808044000/hb2881Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


O—H⋯O hydrogen bonds link the complexes and uncoordinated water molecules into two-dimensional networks parallel to (001).In the title compound, [Ni(C DOI: 10.1107/S1600536809022028/bi2378Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal, adjacent molecules are linked via pairs of N—H⋯O hydrogen bonds into chains propagating in [010].In title compound, [Cu(C DOI: 10.1107/S1600536809044262/hb5128Isup2.hklStructure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF reportAdditional supplementary materials:


The polyoxoanions are linked together via the bipyridyl cations, acting as hydrogen-bond donors, generating a two-dimensional supramolecular network. The asymmetric unit contains 1.5 4,4′-bipyridinium (H2bpy) units, with an inversion centre in the central bond of the second H2bpy unit. The site symmetry of the anion is The title compound, tris diarsenooctadecamolybdate(VI), (C DOI: 10.1107/S1600536809050260/fi2091Isup2.hklStructure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF reportAdditional supplementary materials:


GdIII ions are bridged by bidentate and tridentate 3-PYA ligands, resulting in a two-dimensional structure.In the title compound, [Gd(C DOI: 10.1107/S1600536808012270/lh2617Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The molecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent molecules in the asymmetric unit besides the disordered solvent molecules.The title compound, [Co(C DOI: 10.1107/S1600536808042268/im2092Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536810016466/pk2244Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the structure, the oxalate and 5-aminoisophthalate ligands link the dysprosium ions, building up a two-dimensional metal–organic framework parallel to the (10The title complex, [Dy(C DOI: 10.1107/S1600536809019199/dn2450Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Acta Cr DOI: 10.1107/S1600536809051903/cv2664Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The structure displays weak intramolecular C—H⋯Br hydrogen-bonding interactions.In the title complex, [PtBr DOI: 10.1107/S160053680803208X/rz2250Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, two inversion-related cations are linked to the anion via weak N—H⋯Br hydrogen bonds.In the title compound, (C DOI: 10.1107/S1600536809030323/lh2842Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The CoII centre exists in an all cis-octahedral coordination geometry.In the title compound, [Co(C DOI: 10.1107/S1600536809037878/bt5061Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


All interatomic distances, angles and the hydrogen bond geometry are very similar for the three structures..The title compound, [Pr(C DOI: 10.1107/S1600536809001500/at2681Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Cd atom has a distorted tetrahedral coordination. Intermolecular C—H⋯I hydrogen bonds link the monomeric units, generating a one-dimensional supramolecular chain along the a axis.In the title compound, [CdI DOI: 10.1107/S1600536808030225/bq2097Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The cation and anion are linked by an N—H⋯Br hydrogen bond.The anion in the title compound, (C DOI: 10.1107/S1600536808032248/tk2315Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809032425/hb5049Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Symmetry-related Sn atoms are bridged by diisopropyldithiocarbamoylacetato ligands, forming a one-dimensional polymer along [001].In the title compound, [Sn(C DOI: 10.1107/S1600536810005933/lh2996Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The complex molecules are linked into layers parallel to (001) by N—H⋯N hydrogen bonds, with the H atoms disordered over four symmetry-equivalent non-coordinated N atoms.In the title compound, [Mn(C DOI: 10.1107/S1600536809008411/bi2351Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The metal centre is also chelated by three deprotonated 1,3-diphenylpropane-1,3-dione (dbm) ligands, forming enantiomerically pure [Tb(dbm)3               RRL]. The TbIII atom is located in a distorted square antiprism of eight coordinating atoms (six O and two N atoms).In the title compound, [Tb(C DOI: 10.1107/S1600536809019783/ng2576Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The mean planes of two naphthyl systems of the ligand make a dihedral angle of 40.32 (11)°.In the title complex, [Cu(C DOI: 10.1107/S1600536809030694/hy2212Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The LaIII ions are bridged by μ4-isophthalate ligands, forming two-dimensional layers. In the crystal structure, these layers are connected by intermolecular O—H⋯O hydrogen bonds into a three-dimensional network.In the title coordination polymer, [La DOI: 10.1107/S1600536809054543/lh2972Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808009707/at2559Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.The title compound, [PdCl(C al. 2006. Acta Cr DOI: 10.1107/S1600536810035427/su2207Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, adjacent ZnII atoms are linked by two H2nba ligands, forming one-dimensional ribbons along the c axis. These ribbons are further assembled into layers parallel to the bc plane via O—H⋯O hydrogen bonds.In the title coordination complex, [Zn(C DOI: 10.1107/S1600536809051836/ng2697Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The palladium center has a slightly distorted square-planar environment, with the two P—S chelating ligands adopting a cis configuration. The present structure is a pseudo-polymorph of [Pd(C18H14PS)2]·CH2Cl2.The title compound, [Pd(C DOI: 10.1107/S1600536808026718/bt2741Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Both dithiocarbamate and the N-heterocyclic ligands function in a chelating mode.In the title compound, [Eu(C DOI: 10.1107/S160053680904135X/xu2634Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The title centrosymmetric coordination polymer, {[Cu(C DOI: 10.1107/S1600536810014510/su2168Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Sn atoms in the two independent molecules adopt distorted trans-C3SnO2 trigonal–bipyramidal geometries. The repeat distance of the polymeric chain is b/2.The 4-nitrocinnamate anion in the title compound, [Sn(C DOI: 10.1107/S1600536808032236/tk2314Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


II atom in the title Schiff base complex, [Cu(C15H11N3O5)(C5H5N)], is O,N,O′-chelated by the doubly deprotonated Schiff base ligand. The metal centre is in a square-planar coordination geometry.The pyridine-coordinated Cu DOI: 10.1107/S1600536808042803/bt2838Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808008957/bt2692Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The molecule lies across a twofold rotation axis, around which two 1,10-phenanthroline ligands are arranged. There are short contacts between the 1,10-phenanthroline groups and the O atoms of the croconate ligand, which probably stabilize the crystal structure via weak C—H⋯O interactions.In the title compound, [Zn(C DOI: 10.1107/S1600536808033709/sg2254Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Two independent molecules comprise the asymmetric unit, each of which lies on a mirror plane that passes through the C2Sn unit.In the title compound, [Sn(CH DOI: 10.1107/S1600536809030062/tk2508Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds link the organic cations and the uncoordinated chloride ion.In the title compound, (C DOI: 10.1107/S1600536810002886/hb5291Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Each pair of adjacent MnII atoms is bridged by a CH3O-ip ligand, forming a helical chain running along a crystallographic 21 axis in the c-axis direction. These chains are decorated with 2,2′-bipy ligands on alternating sides. O—H⋯O hydrogen bonding involving the water molecules stabilizes the crystal structure.In the title compound, {[Mn(C DOI: 10.1107/S1600536809035466/bg2299Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The water solvent molecule is disordered over two positions in a 1:1 ratio.In the crystal structure of the title compound, [Ni(N DOI: 10.1107/S1600536809029407/rn2055Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808033102/at2636Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


One 2-dph ligand functions in a bridging mode and connects Pb ions into a linear chain. The crystal packing is governed by intra- and intermolecular O—H⋯O hydrogen bonds.In the title complex, {[Pb(C DOI: 10.1107/S1600536810004162/hy2276Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Two disordered dichloromethane solvent molecules are each 0.25-occupied on a twofold rotation axis.In the title compound, [FePt(C DOI: 10.1107/S1600536808043493/hy2171Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Each FeIII center in the complex has a six-coordinated distorted cis-FeN2O4 octahedral geometry.The structure of the title compound, [Fe DOI: 10.1107/S1600536809005091/hg2478Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, Ph2PN(iPr)PPh2, and two bromide ions in a distorted square-planar geometry.The title compound, [NiBr DOI: 10.1107/S1600536809003936/ci2764Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809038045/hb5109Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The other two imino N atoms act as hydrogen-bond acceptors from phenolate OH groups. The toluene solvent molecule is disordered about a centre of inversion.In the toluene hemisolvated tripodal tris(2-aminoethyl)amine Schiff base, C DOI: 10.1107/S1600536809002906/bt2855Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Fe atom is six-coordinated by three phenolic O and three imine N atoms from three Schiff base ligands in an octahedral geometry.The title complex, [Fe(C DOI: 10.1107/S1600536808014165/sj2500Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The compound adopts a linear chain structure.In the title compound, [CoCl DOI: 10.1107/S1600536808006685/ng2432Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Its non-centrosymmetric polymorph structure, (II), was known previously and has been redetermined at 193 (2) K -μassa 2002. Acta Cr DOI: 10.1107/S1600536809009088/si2150Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Hydrogen bonds exist between the OH group of the pyridine-4-carbaldehyde oxime ligand and the two O atoms of the acetylacetonate ions.The title compound, [U(C DOI: 10.1107/S1600536808012889/im2063Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°. In the title compound, [Au(C DOI: 10.1107/S1600536808027116/hb2785Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The bridging ligand results in an infinite chain. A network of O—H⋯O hydrogen bonds helps to establish the crystal structure.In the title compound, {[Cu(C DOI: 10.1107/S1600536808025439/hb2747Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The two O atoms are cis, as are the two S atoms.In the title compound, [Ni(C DOI: 10.1107/S1600536808017145/hy2137Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808005382/dn2320Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Methanol–acetate O—H⋯O hydrogen bonds link the dinculear units into a linear supramolecular chain extending parallel to [100].The reaction of zinc acetate and 2-methyl-8-hydroxyquinoline in methanol yielded the centrosymmetric dinuclear title compound, [Zn DOI: 10.1107/S1600536809014214/tk2424Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The linear butadiyne substituent has alternating C—C triple and single bonds, while the unsubstituted cyclopentadiene ring is slightly positionally disordered  and retains a close to eclipsed conformation.The title compound, [Fe(C DOI: 10.1107/S1600536809005522/hg2474Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Ni⋯Ni distance is 3.2398 (12) Å.In the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni DOI: 10.1107/S1600536808037902/ci2712Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Two cations are linked into dimers via three bridging carboxylate groups from three 2,5-difluorobenzoic acid units. The GdIII ion is nine-coordinated by seven O atoms and two N atoms.In the centrosymmetric title compound, [Gd DOI: 10.1107/S1600536808023507/er2055Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The Pd atom is located on a centre of inversion.The title compound, [PdCl DOI: 10.1107/S1600536808008337/bt2685Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Two short intramolecular C—H⋯O contacts occur in the molecule.In the centrosymmetric title compound, [Zn(C DOI: 10.1107/S1600536809031109/hb5031Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ferrocenyl unit deviates from an eclipsed geometry with tilted cp rings; the interplanar angle between the cp and imidazole rings is 114.11 (4)°.In the title compound, [Fe(C DOI: 10.1107/S1600536808029231/dn2373Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Extensive O—H⋯O hydrogen-bonding interactions connect the supramolecular chains into a three-dimensional network.The title supramolecular polymer, [Cu(S DOI: 10.1107/S1600536809047096/hb5217Isup2.hklStructure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF reportAdditional supplementary materials:


The MgII ion is hexacoordinated to four tetrahydrofuran (THF) ligands, and two AlH4               − anions through bridging H atoms. The Al—H distances are more precise compared to those previously determined . The molecule has twofold rotation symmetry.The structure of the title compound, [Mg(AlH al. 1995. Chem. BFuhr 2002. J. Allo DOI: 10.1107/S1600536810014200/ci5044Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The SnIV atom is six-coordinate within a distored octahedral geometry defined by a C2Cl2O2 donor set.The molecule of the title compound, [Sn(C DOI: 10.1107/S1600536809039269/tk2538Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The two carboxylate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four MnII atoms, yielding one-dimensional chains extending along [010].The title compound, [Mn DOI: 10.1107/S1600536810008123/fi2094Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The alkyl chains of the ligands are equally disordered over two sets of sites.In the title compound, [Zn(C DOI: 10.1107/S1600536810002825/hb5312Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal, intermolecular O—H⋯O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.In the title compound, [Ni(C DOI: 10.1107/S1600536809028190/cv2585Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The TBDC ligands act as bridging ligands, forming chains along [110]. These chains are further linked into a two-dimensional network via intermolecular O—H⋯O hydrogen bonds. The solvent water molecule lies on a twofold rotation axis.In the title complex, {[Cu(C DOI: 10.1107/S1600536810036913/lh5099Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ions are linked via N—H⋯Cl hydrogen bonds into chains running along the b axis.The crystal structure of the title compound, (C DOI: 10.1107/S1600536808007368/ya2069Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Each Mo atom is coordinated by an η5-cyclopentadienyl ligand, two carbonyl ligands and a diphenylphosphine ligand in a piano-stool fashion.The title compound, [Mo DOI: 10.1107/S1600536808017996/hg2402Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The symmetry-equivalent VV atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is stabilized by weak intermolecular C—H⋯O and C—H⋯F hydrogen bonds.The title compound, [V DOI: 10.1107/S1600536810037232/lh5133Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the b axis.In the title complex, [ZnI DOI: 10.1107/S1600536809037210/om2276Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The metal centres are connected via the tridentate L ligands into a three-dimensional polymeric structure.In the title compound, [Cd(C DOI: 10.1107/S160053680904255X/cv2629Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


J. Soli DOI: 10.1107/S1600536808033394/wm2190Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809003584/hb2904Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The title compound, (C DOI: 10.1107/S1600536810010196/dn2549Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536808036131/pv2114Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The distorted square–pyramidal N2O3 coordination geometry is completed by an O atom derived from a perchlorate anion.In the centrosymmetric and dinuclear title complex, [Mn DOI: 10.1107/S1600536808035551/tk2317Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536809032061/hb5046Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


DOI: 10.1107/S1600536810013541/hb5404Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The bridging phenylcyanamide anions generate an infinite chain propagating in [001].In the title coordination polymer, [Co(C DOI: 10.1107/S160053681000557X/hb5302Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


In the complex cations, the NaI centre is coordinated by five O atoms of the 2,3-naphtho-15-crown-5 ligand and one water O atom. The complex molecules form a two-dimensional network via weak O—H⋯S interactions between adjacent cations and anions The title complex, [Na(C DOI: 10.1107/S1600536809038641/pk2189Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


Intermolecular O—H⋯Cl and O—H⋯O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which consolidates the crystal packing.In the title compound, [CoCl(C DOI: 10.1107/S1600536808042591/cv2481Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The ZnII atom is five coordinate with a distorted trigonal–bipyramidal geometry, coordinating with three N atoms of the Schiff base (2-morpholinoethyl)(2-pyridylmethylidene)amine and two N atoms from two thiocyanate ligands. The morpholine ring adopts a chair configuration.The title compound, [Zn(NCS) DOI: 10.1107/S1600536808044061/su2087Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The metal center is five-coordinate in a trans-Br2SnC3 trigonal bipyramidal geometry. The cation is disordered about a center of inversion.The anion in the title salt, (C DOI: 10.1107/S1600536808011094/sg2227Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The dinuclear complex molecules are assembled into one-dimensional supramolecular chains extending in the [100] direction by hydrogen bonds. Interchain hydrogen bonds further link these chains into layers perpendicular to [001].In the title compound, [Cu DOI: 10.1107/S1600536808034570/cs2084Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


A crystallographic twofold axis bisects the molecule.The title compound, C DOI: 10.1107/S1600536808015377/fj2094Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The word "Initiation" was incorrectly entered as "Initiator." The correct title is: "A Novel Target of Action of Minocycline in NGF-Induced Neurite Outgrowth in PC12 Cells: Translation Initiation Factor eIF4AI". The correct citation is: Hashimoto K, Ishima T (2010) A Novel Target of Action of Minocycline in NGF-Induced Neurite Outgrowth in PC12 Cells: Translation Initiator Factor eIF4AI. PLoS ONE 5(11): e15430. doi:10.1371/journal.pone.0015430


In the crystal structure no obvious hydrogen bonding is observed.The five-coordinate Sn atom in the title salt, [(CH DOI: 10.1107/S1600536809019722/tk2456Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials:


The metal centres are linked in an unusual triple-bridged mode into chains parallel to [101].In the title compound, [Cu(C DOI: 10.1107/S1600536809030050/pv2188Isup2.hkl            Structure factors: contains datablocks I. DOI:  crystallographic information; 3D view; checkCIF report            Additional supplementary materials: